Ancient Japanese company makes modern lithium ion battery with SILX
Mitsui Mining and Smelting, a company with roots that go way back in history, is out to make history in the lithium ion battery market. Known in Japan as Mitsui Kinzoku, they are part of the humungous Mitsui Group whose origins can be traced back to a humble miso shop founded more than a hundred years before the American War of Independence. That's old.
What's new is their breakthrough with silicon-based negative electrode (SILX®) for lithium ion batteries. It seems they've been able to achieve double the energy capacity of a carbon-based negative electrode, boost the energy density 30 to 50 percent and dramatically improve cycle life. What's that mean in English? Their battery could help your electric car accelerate faster, go further and last longer.
Mitsui Mining and Smelting plan on commercializing their technology in 2010. There are still some details like manufacturing processes to work out and the matching of other components like positive electrodes and such. They already have companies knocking on the door for their SILX® and are planning to partner with battery makers and original equipment manufacturers (OEMs) to get their tech in your hands (or car) as quickly as possible. Read more about their battery chemistry and marketing strategy from their press release after the jump.
Press release:
New Lithium-ion Battery Technology Developed
New Silicon-based Negative Electrode (SILX®) Achieves Higher Capacity and Energy Density
Mitsui Mining & Smelting Co., Ltd. (Mitsui Mining & Smelting, President : Yoshihiko Takebayashi) has developed a new Silicon-based negative electrode (SILX®) to be used in rechargeable lithium-ion batteries. SILX® realizes higher capacity and power, which contributes to the further expansion of the batteries useful applications. Mitsui Mining & Smelting aims to begin commercialization of SILX® in the year of 2010, through partnerships with battery manufacturers and OEMs as battery users.
< A new Silicon-based negative electrode with higher capacity and high power >
SILX® has a unique network-structure composed of Silicon and Copper, which introduces improved performance in comparison with Carbon-based negative electrodes currently commercialized in the market. The capacity density of the electrode (*Note 1) will be increased by approximately 100% of today's Carbon-based negative electrodes, and the energy density of battery (*Note 2) will be 30 to 50% higher than current products as well. And SILX® will provide a structurally much larger electric current in longer use.Therefore, a battery using SILX® makes it possible to store more energy (higher capacity) and generate more power (higher output).
< Practical cycle life >
In addition, SILX® first achieved the practical life cycle in the category of new materials for
negative electrode except Carbon. One of the market challenges with developing new negative electrodes using Silicon is maintaining a practical cycle life of the battery. Most systems see significant reductions in a battery useful life, meaning the amount of times a battery can be recharged is significantly reduced. As a Silicon-based negative electrode absorbs lithium-ion from the positive electrode and swells, durable structure and materials are required to realize a long useful life. Mitsui Mining & Smelting accepted this very difficult industry challenge and has demonstrated great success in maintaining a practical cycle life equivalent to existing negative electrodes, by covering Silicon with thin copper (*Note 3) and forming structure with spaces to accommodate the swelling of the cell inside its negative electrode.
< Commercialization through partnerships with companies >
SILX® and basic concept of specifications and structure have already been developed. Mitsui Mining & Smelting is now challenging several subjects such as a suitable combination with positive electrode, establishment of technology for mass production to accelerate commercialization through partnerships with battery manufacturers and OEMs as battery users. Mitsui Mining & Smelting has been working closely with companies from several industries and has received positive feedback regarding SILX®. In Addition, several have expressed interest in creating a business relationship with Mitsui Mining & Smelting for the use of SILX®.
< Business circumstance and prospect >
Lithium-ion batteries are widely used not only for mobile phones, laptop computers, digital still cameras but also power tools and other large energy consumers which require much more power. They are also expected to be employed in the automobile industry which is developing new hybrid and fully electric vehicles that are more fuel efficient and environmentally friendly. Therefore, lithium-ion batteries with higher capacity and power density are required in the market. However, the technologies of the existing batteries using Carbon-based negative electrode have already reached the theoretical bounds to maximize the energy density, and the market demand is directed to negative electrode with newly developed materials, which must be the core element to realize higher performance. No significant materials or concepts of negative electrode have been ensured in the industry so far. SILX®, a newly developed Silicon-based negative electrode overcomes such market difficulties. The development was commenced by a project team under the direct control of the CTO (Chief Technology Officer) based on the company policy of "Front Loading" for manufacturing. By harmonizing and utilizing the technologies from other business units of Mitsui Mining & Smelting such as battery materials, powdering, electrochemistry, and copper foil, the team wasable to achieve success by introducing its advanced technology where others have been less successful.
Mitsui Mining & Smelting is confident that SILX® will extend the application of the rechargeable lithium-ion batteries, and it will contribute to the further expansion of the products to meet the requirements in the society for saving energy, coexistence with environment, development of mobile equipments and so on.
[Source: PCB007]
Reader Comments (Page 1 of 1)
Mort 9:46PM (4/23/2008)
I am glad that the Japanese are working on this battery.
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EVan 10:42PM (4/23/2008)
#1 Mort
Why?
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Cervus 10:52PM (4/23/2008)
This is the kind of news I like to hear lately. I hope the costs are reasonable and it can be commercialized and puts into vehicles as soon as possible.
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Chris M 12:40AM (4/24/2008)
#1 and #2: I'm just glad someone is doing it! This is a different approach from the silicon nanowire being developed at Stanford, and may come to market sooner. Time will tell which approach will ultimately be best.
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greg woulf 6:36AM (4/24/2008)
Argonne just came out with a similar discovery for the cathode. If we could just put the two together we'd be rolling along in our EV's now.
I wish it were all with the same company.
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Domenick Yoney 7:04AM (4/24/2008)
@#5 greg woulf:
We may have covered the Argonne battery work here.
http://www.autobloggreen.com/2008/04/07/battery-breakthroughs-abound/
It's licensed to Japanese company, Toda Kogyo, but according to the source article it wasn't considered too useful for an electric car battery application.
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mamagepstu 11:54AM (4/25/2008)
model of diesel engine cylinder. i want to show the domonstration of working principles of 4-strock cycle
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fnc 1:46PM (4/24/2008)
As I understand it, the need for pure silicon crystals is part of what makes photovoltaics expensive. Would this battery tech suffer from the same problem or is it using silicon in a cheaper form? Of course it could be that it needs so little that the cost of the silicon is only a small percentage of the overall cost anyway (as I understand the lithium in a li-ion battery is). Pricey or not, I hope it works out as they claim it does. I hope to someday drive a car into which I can plug a larger 'gas tank' every few years, and is never more than a few feet from a source of fuel .
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EVan 3:21PM (4/24/2008)
#4 Chris M
I agree, but I just get a little fed up with people who for some reason think the United States isn't capable of high tech. Especially considering that the U.S. is the global leader in the high tech industry and has a greater R&D output than any other continent on earth.
I think it's great a Japanese research company is tackling this, I think it should encourage support for increased American ingenuity.
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BillO 3:42PM (4/25/2008)
Notice that they don't give any actual numbers for energy density. They just say "30 to 50% higher than current products". Well current products vary quite a bit, with lithium-cobalt at almost twice the energy density of lithium-iron.
This is all way too vague to get excited about.
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erinhsing 4:18AM (6/30/2008)
Kaier nano powder of silicon are manufactured by Plasma Arc Vapor Synthesis technology & reactor patented by the Hefei Kaier Nanotechnology Development Co., Ltd. founded in 1999 as a leader manufacturer of nanopowders of refractory non oxide ceramics worldwide.
Silicon(Si) nanopowder are spherical high surface area metal particles. Nanoscale Silicon Particles are typically 20-30 nanometers (nm) with specific surface area (SSA) in the 80 m 2 /g. Surface functionalized nanoparticles allow for the particles to be preferentially adsorbed at the surface interface using chemically bound polymers. Nano silicon powder provide higher activity, good ductile, wide energy gap and high-power lumination. Development research is underway in Nano Electronics and Photonics materials.
Silicon Nanoparticles is suitable for lithium battery electrode materials and have been shown to dramatically expand the storage capacity of lithium ion batteries without degrading the Silicon during the expansion/contraction cycle that occurs as power is charged and discharged. Silicon has long been known to have an excellent affinity for storage of positively charged lithium cations making them ideal candidates for next generation lithium ion batteries.
erin.hsing@yahoo.com
Reply
erinhsing 4:18AM (6/30/2008)
Kaier nano powder of silicon are manufactured by Plasma Arc Vapor Synthesis technology & reactor patented by the Hefei Kaier Nanotechnology Development Co., Ltd. founded in 1999 as a leader manufacturer of nanopowders of refractory non oxide ceramics worldwide.
Silicon(Si) nanopowder are spherical high surface area metal particles. Nanoscale Silicon Particles are typically 20-30 nanometers (nm) with specific surface area (SSA) in the 80 m 2 /g. Surface functionalized nanoparticles allow for the particles to be preferentially adsorbed at the surface interface using chemically bound polymers. Nano silicon powder provide higher activity, good ductile, wide energy gap and high-power lumination. Development research is underway in Nano Electronics and Photonics materials.
Silicon Nanoparticles is suitable for lithium battery electrode materials and have been shown to dramatically expand the storage capacity of lithium ion batteries without degrading the Silicon during the expansion/contraction cycle that occurs as power is charged and discharged. Silicon has long been known to have an excellent affinity for storage of positively charged lithium cations making them ideal candidates for next generation lithium ion batteries.
erin.hsing@yahoo.com
Reply